Hmm, I'm afraid I didn't see your edit till just a few moments ago - I managed to get the effect I wanted by using a layer mask and some very careful work with the sponge tool.
Cheers for the help,
Mike
P.S. I'm very new to Photoshop, though I am aware that the best way to learn it's full potential is just to randomly follow tutorials. Could you share the URL of a decent website for photoshop tutorials that you know of please? I'm currently going through
PSD learning | Learning Resources for Adobe Photoshop however there are relativley few tutorials on there.