I don't use or know anything about Procreate, but any image brought into PS in one of the standard RGB color spaces (eg, sRGB, Adobe RGB, or ProPhoto) will be correctly converted to CMYK values. All of the CMYK numbers are high to give the maximum / deepest blackness (opacity / coverage).
Also, you should be aware that there are literally thousands of different CMYK variants. For each, the CMYK numbers corresponding to RGB = 0,0,0 will each be somewhat different because the printers / inksets / papers to which they apply are different, so, be sure you are using the variant of CMYK that is appropriate for wherever the file is going.
That brings me to my final question / warning. These days, even large volume offset printing operations are accepting, if not actually preferring RGB files instead of risking that their customer (ie, the graphic artist) will do the correct conversion to the variant of CMYK that each of the various offset presses that they may have in their plant needs. Similarly, inkjets certainly shouldn't be fed CMYK files because their printer driver software is specific to that printer and does that conversion automatically for you. So, my question to you is why do you need to make this conversion?
Tom M