insted of making something 'vectorish', why not use a vector program. keep in mind too, that if you save as almost any file format ( .tif, .jpg, .png ) the image will raster anyway. that leaves the vector formats ( .ai, .eps ) the next option would be to up the ppi ( 600 + ) the more pixels per inch, the smoother it will get. be sure you antialias as well
"Things have their shape in time, not space alone. Some marble blocks have statues within them, embedded in their future"