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Hi Paul

Found this, I'm assuming your on Windows

This is a fix suggested a year ago when one uninstalls a previous version and fouls up file associations.  Look similar?? 

 

So I went into the Registry, HKEY_CLASSES_ROOT\Applications\Photoshop.exe\shell\open\command, and changed the (Default) from "C:\Program Files\Adobe\Adobe Photoshop CS5 (64 Bit)\Photoshop.exe" "%1" to "C:\Program Files\Adobe\Adobe Photoshop CS6 (64 Bit)\Photoshop.exe" "%1" (so changed CS5 to CS6) - and now I see 'Adobe Photoshop CS6' in my 'Open with' list when right-clicking an image...

[ATTACH]51424[/ATTACH]

And you could try this if the above doesn't work

http://helpx.adobe.com/creative-suite/kb/cs5-cleaner-tool-installation-problems.html

Forgot to mention if you need to edit the registry just type regedit in the command prompt and when you find the entry just double clink on the word Default to edit it!