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Yes.............just depends on the starting point and what your interpretation of "bolder" might be. There are many adjustments that can be made to make an image bolder. You would have to provide examples of what you consider to be bolder.

When it comes to defining images, it would depend on if we were talking about selections or overall definition of an image. Or maybe General Adjustments to Improve an Image

Making a subject more pronounced or bold could also entail isolating the subject with a selection and blurring the background.

This is a big question with literally hundreds of possible solutions. Depends on what your working with.