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im really confused about what you mean as "vectorised" if your using photoshop then your images will be rasterized.I think this is the case of right tool 4 the job and if your sending things to a paper firm i.e 4 colour print process using litho plates then yeah they will want it as PDF or eps.

And for this you will need a vector based program like illustrator to get the "vectorised" thing that you are talking about.

Adobe illstrator is great for page layout like you are using and has 2 export options...PDF.......and EPS

and if there are images that you have done in ps and want on yoru designs you can place them into your illustrator file.

Photoshop really isnt the right app to b using if you wanna do this easily,id be using illustrator but then i dunno your situation (financial) and whether you can obtain it soon.

other than that i really dunno about achieving what you want in PS cuz well TBH i wouldnt be using it to start with so i wouldnt know(if that makes sense)

sorry if this isnt what you wanted to hear and good luck with it all